catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-diyl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
نویسندگان
چکیده
منابع مشابه
catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-diyl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
The title compound, {(C(14)H(18)N(2))[Pb(2)I(6)]}(n), consists of discrete 1,1'-dimethyl-4,4'-(ethane-1,2-di-yl)dipyridinium cations and one-dimensional [Pb(2)I(6)](n) anions. The organic cation has an inversion center at the mid-point of the ethane C-C bond. In the anion, the Pb(II) atom is coordinated by six I atoms in a distorted octa-hedral geometry. The I atoms bridge the Pb(II) atoms into...
متن کاملThe one-dimensional organic–inorganic hybrid: catena-poly[bis[1-(3-ammoniopropyl)-1H-imidazolium] [[iodidoplumbate(II)]-tri-μ-iodido-plumbate(II)-tri-μ-iodido-[iodidoplumbate(II)]-di-μ-iodido]]
The organic-inorganic hybrid, {(C(6)H(13)N(3))(2)[Pb(3)I(10)]}(n), was obtained by the reaction of 1-(3-ammonio-prop-yl)imidazolium triiodide and PbI(2) at room temperature. The structure contains one-dimensional {[Pb(3)I(10)](4-)}(n) polymeric anions spreading parallel to [001], resulting from face-face-edge association of PbI(6) distorted octa-hedra. One of the Pb(II) cations is imposed at an...
متن کاملcatena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]]
The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluoro-benzyl-idene)amino]-quinolinium cations and a polymeric PbI(3) (-) anion formed by face-sharing PbI(6) octa-hedra. These octa-hedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI(3)](-) fragment are observed in general positions. Polymeric chains are p...
متن کاملcatena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ2 N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
In the title compound, [Cd₂I₄(C₆H₁₄N₂)₂](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octa-hedral coordination environment by four N atoms from two cyclo-hexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordinated by four iodido ligands in a slightly distorted tetra-hedral coordination environment. Two of the iodido ...
متن کاملIodido(tri-tert-butylphosphane-κP)gold(I)
The Au(I) atom of the title compound, [AuI(C(12)H(27)P)], shows an almost linear coordination, with a P-Au-I angle of 178.52 (3)° [Au-P = 2.2723 (14) Å and Au-I = 2.5626 (6) Å].
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s160053681102006x